Category: Articles

A REVIEW ANALYSIS OF GAS HYDRATE TESTS: ENGINEERING PROGRESS AND POLICY TREND.

Environmental Geotechnics Chen, L. Merey, S., Pecher, I. Okajima, J. Komya, A., Diaz-Naveas, J., Li, S., Maruyama, S., Kalachand, S. Kvamme, B., Coffin, R. Methane hydrate has become one promising energy resource for humankind. In this study, recent worldwide onshore/offshore drilling and production activities are analyzed. The most recent reports from sites such as Japan (2013 and 2017) and China (2017) show that the road towards… Read more »

DISSOLVED INORGANIC CARBON PUMP IN METHANE-CHARGED SHALLOW MARINE SEDIMENTS: STATE OF THE ART AND NEW MODEL PERSPECTIVES.

Frontiers in Marine Science. Akam, S.A., Coffin, R.B., Abdulla, H.A., Lyons, T.A. Our data synthesis and broad interpretation emphasizes the importance of SMTZ as not only a methane sink but also an important diagenetic front for global DIC cycling. We further underscore the need to incorporate a DIC pump in methane-charged shallow marine sediments to models for coastal and geologic carbon cycling. This new understanding will… Read more »

CARBON ISOTOPE FORENSICS FOR METHANE SOURCE IDENTIFICATION.

Remediation Coffin, R., Mueller, J. Methane (CH4) in ecosystems originates from ancient petroleum formed deep within the earth and/or via microbial fermentation of organic carbon and subsequent reduction of carbon dioxide (CO2). Given the complexity of different ecosystems, origins of CH4 present can be difficult to determine. This issue was realized in a situation where an antimethanogenic in situ chemical reduction (ISCR) remedial amendment containing organic… Read more »

CO2 RELEASE FROM POCKMARKS ON THE CHATHAM RISE-BOUNTY TROUGH AT THE GLACIAL TERMINATION.

Paleoceanography And Paleoclimatology Stott, L., Davy, B. Shao, J. Coffin, R., Pecher, I., Neil, H., Rose, P. Seafloor pockmarks of varying size occur over an area of 50,000 km2 on the Chatham Rise, Canterbury Shelf and Inner Bounty Trough, New Zealand. The pockmarks are concentrated above the flat‐subducted Hikurangi Plateau. Echosounder data identify recurrent episodes of pockmark formation at ~100,000‐year frequency coinciding with Pleistocene glacial terminations…. Read more »

ATMOSPHERE-OCEAN CO2 EXCHANGE ACROSS THE LAST DEGLACIATION FROM THE BORON ISOTOPE PROXY

Paleoceanography Shao, J., Stott, L., Gray, W.R., Rae, J.W.B., Greenop, R., Pecher, I., Coffin, R.B., Neil, H. Identifying processes within the Earth System that have modulated atmospheric pCO2 during each glacial cycle of the late Pleistocene stands as one of the grand challenges in climate science. The growing array of surface ocean pH estimates from the boron isotope proxy across the last glacial termination may reveal… Read more »

Land and Aquatic Studies: Carbon Stable and Radio Isotope Analysis and More

New writings include articles on the following subjects: Carbon Stable and Radio Isotope Analysis to Identify Methane Sources During a Remedial Action Carbon Isotope Analysis to Confirm Petroleum Natural Attenuation in the Vadose Zone Norfolk Naval Air Base Concentrations and Stable Isotope Values of BTEX in Gasoline-Contaminated Groundwater, Port Hueneme Naval Air Station PAH Source Evaluation, Liepaja Harbor, Latvia Transport, Deposition and Biodegradation of Particle Bound… Read more »

Did My Remedial Amendment Produce All That Methane?

Methanogens/Archaea produce methane. They are often the dominant microbes in reduced environments. Methanogenesis is a requisite component of conventional anaerobic bioremediation. If Archaea are not controlled, then in situ remedial actions employing conventional (i.e., no active control of Archaea) ERD amendments such as oils/lecithins, lactates/sugars, simple hydrogen release compounds or conventional ISCR reagents can generate excessive amounts of methane. At several sites where these conventional ERD/ISCR… Read more »

Stable and Radio Isotope Analysis to Identify Methane Sources During a Remedial Action

Methanogens/Archaea may be dominant microbes in reduced environments, and methanogenesis can be a component of anaerobic bioremediation. If Archaea are not controlled, then in situ remedial actions employing conventional (i.e., no active control of Archaea) amendments such as oils/lecithins, lactates/sugars, simple hydrogen release compounds, conventional/original ISCR reagents, etc. can generate excessive amounts of methane (CH4) during the reduction of carbon dioxide (CO2). Methane can also be… Read more »

Coastal Beaufort Sea Alaskan Shelf Organic Carbon Source(s): Strong Spatial Variations

Carbon isotope geochemistry is applied to understand spatial variation in tundra and methane contribution to coastal shallow sediment cycling across the Alaskan Shelf in the Beaufort Sea. This study shows strong spatial variation in the carbon sources that is a function of tundra melting and riverine input and past ice scouring that is driving sediment deposition and methane production. → Go to Full Report

Dissolved Methane in the Beaufort Sea and the Arctic Ocean, 1992-2009; Sources and Atmospheric Flux

Methane concentration and stable carbon isotope ratios measured from ice and ice free waters along the Alaskan Shelf in the Beaufort Sea between 1992 and 2009 show strong spatial variation in flux rates to the atmosphere.  Isotope analysis indicated the primary source of the methane is bacterial.  The estimate from this region on the total contribution to the atmosphere is only 0.42% of the total annual loading of… Read more »